Clariant’s Exolit® OP 560 confirmed as safer flame retardant for PU foam
- United States Environmental Protection Agency concludes assessments of flame retardants
- Non-halogenated Exolit OP 560 identified as safer alternative to pentaBDE for PUR foams
- Supports upholstery sector in switch to renewable materials and enhanced environmental compatibility
The report is part of the EPA’s Design for the Environment program, which helps industries choose safer chemicals, and offers a basis for future decision-making by providing a detailed comparison of the potential public health and environmental impacts of chemical alternatives.
Exolit OP 560 is a reactive flame retardant that eliminates unwanted emissions since it becomes chemically bonded within the polymeric polyurethane foam structure. As a result, the Exolit OP 560 cannot leave the foam during use. Exolit OP is also halogen-free, and has a more favorable toxicological and environmental profile. In particular, it cannot bioaccumulate in humans and other organisms since it is "locked" into the foam. Further benefits for PU applications include excellent ageing stability, as well as low smoke density and smoke gas corrosivity in case of a fire. The phosphonate’s high effectiveness and good compatibility with natural polymers allow it to be used at low dosages in the foam matrix, which also adds to the foam’s excellent sustainability profile.
Natural Foams Technology (formerly Green Urethanes Ltd), the provider of green solutions to the global PU industry, has confirmed that manufacturers can use Exolit OP 560 with its natural oil polyol (NOP) foams to develop low-emission flexible foams that meet internationally accepted flammability standards such as TB117-1975, California’s open flame flammability test for upholstered furniture, and the updated Cal TB 117-2013, which comes into force in January 2015. With high bio-renewable content, the foams have become the first to be accepted into the USDA’s BioPreferred program, a U.S. federal program to encourage industry to switch to more sustainable materials.
NCFI Polyurethanes, a North Carolina-based manufacturer, has been utilizing the NOP technology in their BioLuxMax line for several years. After running extensive trials with Exolit OP 560, they plan to introduce a commercial product in the 4th quarter 2014. "This is a natural evolution for our BioLuxMax initiative," says Chris Bradley, VP of Consumer Products for NCFI. "This project has always been about maximizing the benefits we can offer our customers. We feel a foam with 33% certified bio-renewable content that passes the open flame standard of CA-117-1975 and can be labeled under the new California law as flame retardant free, is a huge step in that direction."
Additional testing by Clariant and Natural Foams reinforces the EPA’s replacement assessment of the Exolit material. Results from these and other independent tests show good flame retardant performance as well as substantial smoke reduction from these foams. A recent study4 by Dr. Heather Stapleton at Duke University’s Nicholas School for the Environment in North Carolina also concluded that Exolit OP 560 is not released from the polyurethane foam.
"Exolit OP 560 is not only halogen-free but becomes an integral part of the PU foam, creating possibilities to produce flexible foams with locked-in fire protection without the environmental and health concerns of traditional flame retardants," comments Adrian Beard, Head of Marketing Flame Retardants, Clariant. "The US-EPA report is a step forward in easing the identification of safer alternatives by PU foam producers and end-users."
Clariant is looking to expand capacity to meet increasing demand in the move toward more environmentally friendly and sustainable PU foams.
1 US-EPA foam flame retardant draft update report - http://www.epa.gov/dfe/pubs/projects/flameret/about.htm 2 US-EPA Press release - http://yosemite.epa.gov/opa/admpress.nsf/0/F943A4C163A5B8A785257CF500698492 3 Jeff Rowlands: Natural Foams Technology to produce safer and more environmentally acceptable flexible PU foams. PU MAGAZINE – VOL. 11, NO. 4 – Aug./Sep. 2014 -- http://naturalfoams.com/wp-content/uploads/2014/09/Special-Reprint-Natural-Foams-Technology-PU-Magazine-August-2014.pdf 4 E M Cooper, G L Kroeger, K Davis, P L Ferguson, H M Stapleton: Duke Superfund Center Foam Project: Flame Retardant Testing for the General Public. Poster presented at BFR 2014 conference, Indianapolis, IN, USA -- http://naturalfoams.com/wp-content/uploads/2014/09/BFR_2014_Final1.pdf
This information corresponds to the present state of our knowledge and is intended as a general description of our products and their possible applications. Clariant makes no warranties, express or implied, as to the information’s accuracy, adequacy, sufficiency or freedom from defect and assumes no liability in connection with any use of this information. Any user of this product is responsible for determining the suitability of Clariant’s products for its particular application.<br /> <br /> * Nothing included in this information waives any of Clariant’s General Terms and Conditions of Sale, which control unless it agrees otherwise in writing. Any existing intellectual/industrial property rights must be observed. Due to possible changes in our products and applicable national and international regulations and laws, the status of our products could change. Material Safety Data Sheets providing safety precautions, that should be observed when handling or storing Clariant products, are available upon request and are provided in compliance with applicable law. You should obtain and review the applicable Material Safety Data Sheet information before handling any of these products. For additional information, please contact Clariant.<br /> <br /> * For sales to customers located within the United States and Canada the following applies in addition: No express or implied warranty is made of the merchantability, suitability, fitness for a particular purpose or otherwise of any product or service.<br /> <br /> © Trademark of Clariant registered in many countries.<br /> ® 2019 Clariant International Ltd