Exolit® OP 1240

Phosphinate flame retardant for polyester injection moulding applications

Edition Date :
January 16, 2014

Exolit OP 1240 is a flame retardant based on an organic aluminium phosphinate which is a thermally stable white solid without any hazard classification or labeling. It can be easily compounded into polyesters and subsequently processed again to manufacture flame retarded parts used in consumer or industrial products.

For more details see our Innovation Spotlight video.

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  • Benefits

    • Non-hygroscopic, insoluble in water and organic solvents
    • High efficiency due to its high phosphorus content
    • UL 94 V-0 rating down to 0.4 mm thickness
    • Suitable for PET sheet extrusion
    • Suitable for both glass fibre reinforced and unreinforced grades
    • The flame retarded polyester compounds exhibit good physical and excellent electrical properties
    • Good colorability
    • Versatile use with synergists
    • Non-halogenated flame retardant with favorable environmental and health profile
  • Safety and MSDS

    Further safety data and handling information are available from our current Material Safety Data Sheet. For disposal in accordance with the regulations the product should be treated as special waste and taken to a suitable incineration plant.   

    Contact Us
    Please contact us for safety and regulatory details or the Material Safety Data Sheet (MSDS).
  • Specifications

    Characteristics  Unit Target Value DS¹)  TD²)   Test Method 
    Phosphorus  %(w/w) 23.3 - 24.0  

    Photometry after oxidizing dissolution; (11/17) or wavelength dispersive X-ray fluorescence spectrometry; (11/23)  
    Water / Moisture  %(w/w) max. 0.2  

    Thermogravimetry; (11/03)  
    Density  g/cm³ 1.35  

    at 20° C  
    Bulk Density  kg/m³    400 - 600  

    Decomposition Temperature  °C  > 300  

    (TGA 2% weight loss)  
    Average Particle Size (D50)  µm    25 - 50  

    ¹) Delivery specification: The product is monitored on a regular basis to ensure that it adheres to the specified values. Test methods: Clariant method numbers 11/xx in brackets.
    ²) Technical data: The technical data are used solely to describe the product and are not subject to regular monitoring.  
  • Applications

    Exolit OP 1240 is a flame retardant for thermoplastics and thermosets. Due to its high phosphorus content the product is distinguished by a high efficiency.

    Exolit OP 1240 was developed especially for the use in polyesters. It is suitable for both glass fibre reinforced and unreinforced grades. The flame retarded polyester compounds exhibit very good physical and electrical properties.

    In PBT, a dosage of 20 % (by wt.) Exolit OP 1240 is usually sufficient to obtain the UL 94 V-0 classification for electrical components (at 1.6 as well as 0.8 mm thicknesses). In PET, less than 15 % are required to pass UL 94 V-0. Synergistic effects are known with other flame retardants like melamine polyphosphate, melamine cyanurate or zinc borates.

    Subject to the polymer grade, processing conditions and glass fibre reinforcement the dosage of the flame retardant may vary.
  • Packaging and Handling

    Delivery form
    White powder

    Packaging
    Exolit OP 1240 is delivered in 20 kg paper bags with PE inliner or 500 kg big bags.

    Storage
    Minimum shelf life is 12 months from the date of shipping when stored according to the said conditions.     
  • EcoTain

    PeoplePEOPLE
    People
      Non hazardous, studies on life cycle data available.
    People
      Saves lives and assets as a (halogen free) flame retardant. Supports the attainability of eco-lables for customer products.
    PeoplePLANET
    People
      Phosphorus is on the EU list of critical raw materials but recycling is possible and actively investigated.
    People
      Very efficient production process with high yield, minimized waste and low water consumption.

     

      PeoplePERFORMANCE   
      People
        Extensive work with customers along the value chain, optimizing material performance and evaluating life cycle aspects with stakeholders.
      People
        Efficient at comparatively low loadings. Synergies with other halogen free flame retardants. High tracking resistance in E&E applications.
    • More Information

      For more details see our Innovation Spotlight video.
    • Processing

      Before incorporating Exolit OP 1240, it is important to predry the polyester as usual. If possible, the resulting moisture content should be below 0.05% (by wt.) for PBT and 0.005% for PET. Predrying of Exolit OP 1240 is not necessary. However, predrying (e. g. 4h at 120 °C) is recommended, if even very low moisture contents must be avoided.

      Wear and corrosion protected screw elements are recommended when using Exolit OP 1240 in reinforced polyesters.

      The mixing and processing methods customary in powder processing of polymers can be used with Exolit OP 1240. The VDI Guideline 2263 “Prevention of dust fires and dust explosions” or the relevant national regulations must be observed. The optimum conditions for incorporating should be determined in each individual case. Care must be taken to ensure homogeneous dispersion of all components. The temperature of the polymer melt should not exceed 320 °C.

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    Disclaimer:
    This information corresponds to the present state of our knowledge and is intended as a general description of our products and their possible applications. Clariant makes no warranties, express or implied, as to the information’s accuracy, adequacy, sufficiency or freedom from defect and assumes no liability in connection with any use of this information. Any user of this product is responsible for determining the suitability of Clariant’s products for its particular application. 
    

    * Nothing included in this information waives any of Clariant’s General Terms and Conditions of Sale, which control unless it agrees otherwise in writing. Any existing intellectual/industrial property rights must be observed. Due to possible changes in our products and applicable national and international regulations and laws, the status of our products could change. Material Safety Data Sheets providing safety precautions, that should be observed when handling or storing Clariant products, are available upon request and are provided in compliance with applicable law. You should obtain and review the applicable Material Safety Data Sheet information before handling any of these products. For additional information, please contact Clariant.

    * For sales to customers located within the United States and Canada the following applies in addition: No express or implied warranty is made of the merchantability, suitability, fitness for a particular purpose or otherwise of any product or service.

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