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Highly stable phosphinate based flame retardant for polyamide

Exolit™ OP 1480

Exolit OP 1480 is a non-halogenated flame retardant based on organic phosphinates for polyamide. The product achieves its flame-retardant effect through a combined gas phase and condensed phase mode of action. Compared to Exolit OP 1400, Exolit OP 1480 gives an improved performance in the glow wire ignition temperature (GWIT according to IEC 60695). The product is a new synergistic flame-retardant formulation. Exolit OP 1480 is based on a new chemical substance which is currently being registered in various national and regional chemical inventories.

For more details see our Innovation Spotlight video.

Benefits
  • High GWIT of at least 775°C in all thicknesses (0.75 mm – 3 mm)
  • UL 94 V-0 rating down to 0.4 mm thickness
  • Suited for applications in hot and humid settings
  • Outstanding thermal stability, wide processing window
  • The flame retarded polyamide compounds exhibit very good physical and excellent electrical properties
  • Good performance in cone calorimeter: low peak heat release and low smoke density
  • Low material density
  • Good colorability
Safety

For regulatory details such as the classification and labelling as dangerous substances or goods please refer to our corresponding Material Safety Data Sheet. For disposal in accordance with the regulations the product should be treated as special waste and taken to a suitable incineration plant.

Technical Data

 

 

 

 Test method

Phosphorus

 % (w/w)

approx. 12.5

Photometry after oxidizing dissolution (11/17) or wavelength dispersive X-ray fluorescence spectrometry (11/23)

Moisture content

% (by wt.)

max. 2.0

 Karl-Fischer titration (11/21)

Density at 23°C

g/cm3

approx. 1.6

 

Bulk Density

kg/m3

approx. 520

 (DIN 53466)

Application

Exolit OP 1480 was developed especially for polyamides. It is suited for polyamide 6 and polyamide 66 as well as polyphthalamides and other high temperature polyamides, e.g. PA 46, for both glass-fiber-reinforced and unreinforced grades. Exolit OP 1480 was optimized for PA66 GF30 to pass at least GWIT 775°C as well as UL 94 V-0.  The flame retarded polyamide compounds with Exolit OP 1480 exhibit very good physical and electrical properties and they are suitable for applications also in hot and humid settings.

Formulation

In glass-fiber-reinforced polyamide 6 and polyamide 66  a dosage of about 20-24 % (by wt.) of Exolit OP 1480 is usually sufficient to obtain GWIT of 775°C and the UL 94 V-0 classification for electrical components (at 1.6 mm as well as 0.8 mm and 0.4 mm thickness). Especially for thin applications, it is recommended to add antidripping agents like PTFE in case dripping in UL 94 test must be avoided.

 

In semi-aromatic polyamides the dosage can be reduced to approx. 15% for UL 94 V-0 and GWIT of 850°C.  Subject to the polymer grade, processing conditions and glass-fiber reinforcement the dosage of the flame retardant may vary.

Processing

Before incorporating Exolit OP 1480, it is important to pre-dry the polyamide as usual. If possible, the resulting moisture content should be below 0.1 % (by wt.). Predrying of Exolit OP 1480  is not necessary. However, pre-drying (e.g. 4 h at 120 °C) is recommended, if even very low moisture contents must be avoided.

The mixing and processing methods customary in powder processing of polymers can be used with Exolit OP 1480. The VDI Guideline 2263 Prevention of dust fires and dust explosions or the relevant national regulations must be observed.

The optimum conditions for incorporating should be determined in each individual case. Care must be taken to ensure homogeneous dispersion of all components. The temperature of the polymer melt should not exceed 340 °C.

Packaging and Handling

Delivery form
Powder

Packaging
Exolit OP 1480 is delivered in 20 kg bags.

Storage
The product should be stored at a dry place at room temperature. Opened containers should be tightly resealed after use.

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